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Should I use URL encoding for doi links, or does it matter?

I summarize research articles of interest to my readers, for example at https://www.ptsdexams.net/disability-exams-research.html .

I usually include the Digital Object Identifier (doi), either by itself, e.g., doi:10.1007/s12207-019-09367-5 or as a link, e.g., https://doi.org/doi:10.1007/s12207-019-09367-5.

I noticed today that a link contained unusual characters (for a doi link), that I learned is URL encoding to a valid ASCII format, specifically %2F instead of a forward slash (/).

I also noticed that if I use the URL without the URL encoding, it still works, although Chrome converted the URL.

https://doi.org/10.1007/s12207-019-09349-7https://doi.org/10.1007%2Fs12207-019-09349-7

Firefox, Edge, and Opera did not convert the URL, although either URL worked on those browsers.

It seems to my less-knowledgeable mind that it does not make a difference which URL I use on my website, but I want to ask the experts to make sure. Thus, my question: Should I use URL encoding for doi links, or does it matter?