And I have submitted sitemaps using Google webmaster tools (28 webpages and 68 images). The status of indexing shown is pending. I had submitted 2 days before. If the status on webmaster is pending then how come google shows 94 results on my website name?? Does that mean my website is been crawled as well as indexed? Is this a good thing?
As Google indexed your site the indexed pages and keywords are added into the index in near real time and go live into production. The reason why the index status is pending is because the crawl and evaluation of keywords has not yet been fully completed. For a new site this can take up to two weeks at times though frequently it is faster than that.